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李珺老师介绍
李珺 性别：女 民族：汉
部门：无机化学与材料化学学部 出生年月：1966-06-22
职称：教授/博士生导师
邮箱：junli@nwu.edu.cn
研究方向： 1.功能配合物化学 2.卟啉及金属卟啉合成及性能 3.有机/无机复合材料制备及催化
简 介
李珺，教授，博士生导师，西北大学国家级化学实验教学示范中心主任。1988年毕业于陕西师范大学化学系教育专业本科，1991年获陕西师范大学无机化学专业硕士学位，1991年至今在西北大学化学系从事教学和科研工作，期间，2001年获西北大学无机化学专业博士学位，2002－2003年在山西大学分子科学研究所博士后站工作，2004－2007年期间，先后两年在意大利Lecce大学工学院从事材料合成与催化方面的研究工作。近年来主持国家自然科学基金,陕西省自然科学基金,陕西省国际合作项目,陕西省教委专项和校内基金等多项，主持完成的成果"植物生理功能锰酶模型配合物和脲类体系配合行为研究"年获陕西省高校科学技术奖一等奖。主编出版教材综合化学实验，并获西北大学教学成果二等奖。
近期代表性论文：
[1]Novel meso-substituted porphyrins:synthesis,characterization and photocatalytic activity of their TiO2-based composites.Dye and Pigments,2009,80:321-328.
[2]Synthesis of novel porphyrins cardanol based via cross metathesis. Catalysis Today 140 (2009) 37–43.
[3]Synthesis,crystal structures,and catalytic hydrolysis activities of four dinuclear complexes with 1,4,7,10-tetraazacyclododecane and succinate ligands.Transition Metal Chemistry,2009,34(2):191-196.
[4]A dinuclear diamagnetic copper(II)complex[Cu2(ophen)2]Cl2 with hydroxylated phen.Journal of Coordination Chemistry,2008,61:24,4033-4039.
[5]Synthesis,structures and properties of cobalt(III)and iron(III)complexes with anew triazamacrocycle derivative ligand 1,4-diacetate-1,4,7-triazacyclodecane.J.of Coordination Chemistry,2008,61(22):3610–3619.
[6]Fine chemicals from Cardanol via Cross metathesis reaction. Chemistry Today ? 2008, 26( 3):72-74.
[7]Efficient degradation of 4-nitrophenol by using functionalized porphyrin-TiO2 photocatalysts under visible irradiation.Applied Catalysis B:Environmental,2007,76:218-226.
[8]TiO2-based photocatalysts impregnated with metallo-porphyrins employed for degradation of 4-nitrophenol in aqueous solutions:role of metal and macrocycle.Res.Chem.Intermed.,2007,33(3–5):433–448.
[9]Two novel two-dimensional frameworks with channels built from hydrogen bonds:structures and properties study on copper(II)and nickle(II)complexes of the macrocyclic ligand 1,4,7-triazacyclodecane(tacd).J.of Chemical Crystallography,2007,Vol.37,No.4:255-263.
[10]Crystal Structures and Theoretical Calculation of Zn(II)and Cu(II)Supramolecular Complexes Based on Macrocyclic Triamine Ligand 1,4,7-Triazacyclodecane(tacd).Chinese Journal of Chemistry.2007,25(06):784-790.
[11]Crystal structure,magnetic property and thermal analysis of anovel manganese complex with phenyldicarboxylate and benzidine ligands.Structural chemistry,2006,17:327-331.
[12]Carboxy Ester Hydrolysis Promoted by Two New Bimetallic Macrocyclic Complexes:Synthesis,Characterization and Catalytic Activity.Transition Metal Chemistry.2006,31(5):611-615.
[13]Synthesis,Structure and Thermal Decomposition of Anovel One-Dimensional Chain Complex of Manganese(II)with 2,2’-Diphenic Acid and 1,10-Phenanthroline.J.of Structural Chemistry,2005，46(2)：361-365.
[14]Synthesis,Structure and Characterization of aSeries of Transition Metal Complexes With Tripodal Polyimidazole Ligand,Chinese Journal of Chemistry.，2005，23(2)：132-136.
[15]Crystal Structure and Characterization of aNew Mixed-valence Manganese(III/IV)Complex:[Mn2(cyclen)2(μ-O)2](ClO4)3?4H2O.Chinese Journal of Chemistry.，2005，23(4):418-420.
[16]Reconstruction of the water-oxidizing complex in manganese-depleted Photosystem II using synthetic manganese complexes.Journal of Photochemistry and Photobiology B:Biology 81(2005)114-120.
[17]Study on the Thermal Decomposition Kinetics of cis(trans)-[Cu(gly)2].H2O.Science in China Ser.B Chemistry,2005(48Supp.):70-73.
[18]Synthesis and Crystal Structure of aNovel Two-dimensional Network Complex[Mn(O2CCH2Cl)2(phen)]n.Science in China Ser.B Chemistry,2005(48Supp.):79-82.
[19]Synthesis,crystal structures and thermal decomposition of two novel supramolecular complexes[Ni(cyclen)(H2O)2](tpa)and[Cu(cyclen)H2O](tpa).3H2O(cyclen=1,4,7,10-tetraazacylododecane,tpa=dianion of terephalic acid).Structure Chemistry,2005,16(4):439-444.
[20]Crystal Structure of aNickel(II)Complex with Macrocyclic Tetraamine.J.of Chem.Crystalllography.2004,34(7):409-413.
[21]Poly[manganese(II)]-2-benzidine-κ2 N：N-3-biphenyl-2,2'-carboxylatoκ4-O,O',O',O"].Acta Cryst.,2004,C60,m501–m503.
[22]Thermal Kinetic TG-analysis of metal oxalate complexes.Thermochimica Acta,2003,406:77-87.
[23]Synthesis,Structure and Magnetic Properties of aNew Oxo-Centered Mixed-Valent Trinuclear Manganese Complex,Inorganic chemistry communications,2002,5:51-55.
[24]混合价双核锰配合物[(Phen)2Mn(μ-O)2Mn(Phen)2]ClO4?CH2ClCOOH?2H2O的合成与表征,高等学校化学学报，2002,23(1):24~26.
[25][Mn3O(O2CC6H5)6(C3H4N2)3]C6H5CO2.0.5H2O的合成,晶体结构及磁性质,化学学报,2001,59(7):1116.
[26]Synthesis,crystal structure and properties of binuclear manganese complex[(bipy)2Mn2(μ-O)(μ-Ac)2(H2O)2](ClO4)2，Chinese Science Bulletin,2000,45(12):1079.
[27]双核锰配合物[(phen)2Mn2(μ-O)(μ-Ac)2(H2O)2](ClO4)2.4H2O的合成晶体结构及性能，高等学校化学学报,2000,21(7):836
[28]Synthesis,structure and magnetic properties of oxo-centered trinuclear manganese complex[Mn3O(O2CC3H7)6(C5H5N)3]ClO4，Inorganica Chimica Acta 1999,294(1):109.
部门：无机化学与材料化学学部 出生年月：1966-06-22
职称：教授/博士生导师
邮箱：junli@nwu.edu.cn
研究方向： 1.功能配合物化学 2.卟啉及金属卟啉合成及性能 3.有机/无机复合材料制备及催化
简 介
李珺，教授，博士生导师，西北大学国家级化学实验教学示范中心主任。1988年毕业于陕西师范大学化学系教育专业本科，1991年获陕西师范大学无机化学专业硕士学位，1991年至今在西北大学化学系从事教学和科研工作，期间，2001年获西北大学无机化学专业博士学位，2002－2003年在山西大学分子科学研究所博士后站工作，2004－2007年期间，先后两年在意大利Lecce大学工学院从事材料合成与催化方面的研究工作。近年来主持国家自然科学基金,陕西省自然科学基金,陕西省国际合作项目,陕西省教委专项和校内基金等多项，主持完成的成果"植物生理功能锰酶模型配合物和脲类体系配合行为研究"年获陕西省高校科学技术奖一等奖。主编出版教材综合化学实验，并获西北大学教学成果二等奖。
近期代表性论文：
[1]Novel meso-substituted porphyrins:synthesis,characterization and photocatalytic activity of their TiO2-based composites.Dye and Pigments,2009,80:321-328.
[2]Synthesis of novel porphyrins cardanol based via cross metathesis. Catalysis Today 140 (2009) 37–43.
[3]Synthesis,crystal structures,and catalytic hydrolysis activities of four dinuclear complexes with 1,4,7,10-tetraazacyclododecane and succinate ligands.Transition Metal Chemistry,2009,34(2):191-196.
[4]A dinuclear diamagnetic copper(II)complex[Cu2(ophen)2]Cl2 with hydroxylated phen.Journal of Coordination Chemistry,2008,61:24,4033-4039.
[5]Synthesis,structures and properties of cobalt(III)and iron(III)complexes with anew triazamacrocycle derivative ligand 1,4-diacetate-1,4,7-triazacyclodecane.J.of Coordination Chemistry,2008,61(22):3610–3619.
[6]Fine chemicals from Cardanol via Cross metathesis reaction. Chemistry Today ? 2008, 26( 3):72-74.
[7]Efficient degradation of 4-nitrophenol by using functionalized porphyrin-TiO2 photocatalysts under visible irradiation.Applied Catalysis B:Environmental,2007,76:218-226.
[8]TiO2-based photocatalysts impregnated with metallo-porphyrins employed for degradation of 4-nitrophenol in aqueous solutions:role of metal and macrocycle.Res.Chem.Intermed.,2007,33(3–5):433–448.
[9]Two novel two-dimensional frameworks with channels built from hydrogen bonds:structures and properties study on copper(II)and nickle(II)complexes of the macrocyclic ligand 1,4,7-triazacyclodecane(tacd).J.of Chemical Crystallography,2007,Vol.37,No.4:255-263.
[10]Crystal Structures and Theoretical Calculation of Zn(II)and Cu(II)Supramolecular Complexes Based on Macrocyclic Triamine Ligand 1,4,7-Triazacyclodecane(tacd).Chinese Journal of Chemistry.2007,25(06):784-790.
[11]Crystal structure,magnetic property and thermal analysis of anovel manganese complex with phenyldicarboxylate and benzidine ligands.Structural chemistry,2006,17:327-331.
[12]Carboxy Ester Hydrolysis Promoted by Two New Bimetallic Macrocyclic Complexes:Synthesis,Characterization and Catalytic Activity.Transition Metal Chemistry.2006,31(5):611-615.
[13]Synthesis,Structure and Thermal Decomposition of Anovel One-Dimensional Chain Complex of Manganese(II)with 2,2’-Diphenic Acid and 1,10-Phenanthroline.J.of Structural Chemistry,2005，46(2)：361-365.
[14]Synthesis,Structure and Characterization of aSeries of Transition Metal Complexes With Tripodal Polyimidazole Ligand,Chinese Journal of Chemistry.，2005，23(2)：132-136.
[15]Crystal Structure and Characterization of aNew Mixed-valence Manganese(III/IV)Complex:[Mn2(cyclen)2(μ-O)2](ClO4)3?4H2O.Chinese Journal of Chemistry.，2005，23(4):418-420.
[16]Reconstruction of the water-oxidizing complex in manganese-depleted Photosystem II using synthetic manganese complexes.Journal of Photochemistry and Photobiology B:Biology 81(2005)114-120.
[17]Study on the Thermal Decomposition Kinetics of cis(trans)-[Cu(gly)2].H2O.Science in China Ser.B Chemistry,2005(48Supp.):70-73.
[18]Synthesis and Crystal Structure of aNovel Two-dimensional Network Complex[Mn(O2CCH2Cl)2(phen)]n.Science in China Ser.B Chemistry,2005(48Supp.):79-82.
[19]Synthesis,crystal structures and thermal decomposition of two novel supramolecular complexes[Ni(cyclen)(H2O)2](tpa)and[Cu(cyclen)H2O](tpa).3H2O(cyclen=1,4,7,10-tetraazacylododecane,tpa=dianion of terephalic acid).Structure Chemistry,2005,16(4):439-444.
[20]Crystal Structure of aNickel(II)Complex with Macrocyclic Tetraamine.J.of Chem.Crystalllography.2004,34(7):409-413.
[21]Poly[manganese(II)]-2-benzidine-κ2 N：N-3-biphenyl-2,2'-carboxylatoκ4-O,O',O',O"].Acta Cryst.,2004,C60,m501–m503.
[22]Thermal Kinetic TG-analysis of metal oxalate complexes.Thermochimica Acta,2003,406:77-87.
[23]Synthesis,Structure and Magnetic Properties of aNew Oxo-Centered Mixed-Valent Trinuclear Manganese Complex,Inorganic chemistry communications,2002,5:51-55.
[24]混合价双核锰配合物[(Phen)2Mn(μ-O)2Mn(Phen)2]ClO4?CH2ClCOOH?2H2O的合成与表征,高等学校化学学报，2002,23(1):24~26.
[25][Mn3O(O2CC6H5)6(C3H4N2)3]C6H5CO2.0.5H2O的合成,晶体结构及磁性质,化学学报,2001,59(7):1116.
[26]Synthesis,crystal structure and properties of binuclear manganese complex[(bipy)2Mn2(μ-O)(μ-Ac)2(H2O)2](ClO4)2，Chinese Science Bulletin,2000,45(12):1079.
[27]双核锰配合物[(phen)2Mn2(μ-O)(μ-Ac)2(H2O)2](ClO4)2.4H2O的合成晶体结构及性能，高等学校化学学报,2000,21(7):836
[28]Synthesis,structure and magnetic properties of oxo-centered trinuclear manganese complex[Mn3O(O2CC3H7)6(C5H5N)3]ClO4，Inorganica Chimica Acta 1999,294(1):109.
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