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胡怀明老师介绍
胡怀明 性别：男 民族：汉
部门：物理化学学部 出生年月：1964-5-22
籍贯：陕西府谷 职称：教授/博士生导师
邮箱：ChemHu1@nwu.edu.cn 电话： 029－88303331(O)
研究方向： 结构化学；晶体工程；发光材料化学
简 介
胡怀明，男，博士，教授，博士生导师，生于1964年5月。现任西北大学教授，中国晶体学会小分子委员会委员,陕西省分析测试协会理事。1981.9~1985.7：在延安大学化学系化学专业学习，获学士学位。1985.9~1988.7：在兰州大学化学系物理化学专业读硕士研究生，获硕士学位。1988.8~1994.2：在陕西师范大学化学系任助教及讲师。1994.3~1997.7：在南京大学配位化学研究所做博士研究生，获博士学位。1997.9~1999.5：在中国科学院福建物质结构研究所做博士后，主要研究大环配合物的合成和结构。1999.5~2000.5：在德国鲁尔波鸿大学（Ruhr-Universit?t Bochum）无机化学I系做博士后，主要研究金属硅氧烷的合成和结构。2000.5~2003.9：在中国科学院化学研究所任副研究员，主要从事晶体结构分析和化学结晶学研究。2002.5~2003.6：在英国伯明翰大学(University of Birmingham)化学学院做访问研究，主要研究稀土配合物的结构和发光性质。目前主要从事稀土和过渡金属配合物的结构化学和发光性能研究。稀土离子具有线状光谱,长寿命和大斯托克斯位移的独特光学性质，在生物体系的荧光免疫分析,临床诊断,显示器件,发光传感器,激光材料和远程通讯等领域具有潜在的应用。我们设计合成出能够对紫外光有强吸收的,能够把吸收的能量有效传递给稀土离子,并能保护稀土离子的激发态不进行非辐射去活的有机配体，然后自组装出发光性能优异的化合物。主持教育部留学回国人员科研启动基金，人事部留学回国人员基金，陕西省自然科学研究计划项目（2004B09），陕西省教育厅自然科学专项(07JK385)，国家自然科学基金(20573083, 20873098)等。在Angew. Chem. Int. Ed.,Chem. Eur. J.,Chem. Commun.,J. Chem. Soc.，Dalton Trans.,Inorg. Chem.,New J. Chem.,Organometallics,Eur. J. Inorg. Chem.,Polyhedron,Inorg. Chim. Acta等SCI期刊上发表学术论文100多篇。
一,学历：
1981.9-1985.7 延安大学化学系化学专业学习，获学士学位。
1985.9-1988.7 兰州大学化学系物理化学专业学习，获硕士学位。
1994.3-1997.7南京大学配位化学研究所无机化学专业学习，获博士学位。
二,工作经历：
1988.8-1994.2陕西师范大学化学系助教及讲师。
1997.9-1999.5中科院福建物质结构研究所做博士后研究。
1999.5-2000.5德国鲁尔波鸿大学(Ruhr-Universit?t Bochum)做博士后研究。
2000.5-2003.9中国科学院化学研究所X射线衍射室副研究员，负责X射线衍射工作和相关的研究工作。其中，2002.5-2003.6获英国皇家化学会基金资助,在英国伯明翰大学(Birmingham University)做访问研究。
2003.10- 西北大学教授，从事结构化学和化学结晶学的教学和科研工作。
三．主持的在研项目：
1. 国家自然科学基金(20573083)
项目的名称: 过渡金属配位结构单元调控镧系离子近红外发光的研究
经费来源：国家自然科学基金委
2. 国家自然科学基金 (20873098)
项目的名称: beta-二酮基双极配体的间隔臂调控镧系配合物近红外发光性能的研究
经费来源：国家自然科学基金委
3. 陕西省教育厅自然科学专项 (07JK385)
项目的名称: 稀土双β-二酮配合物的合成,结构和发光性质研究
经费来源：陕西省教育厅
四．发表论文：
1. Xiao-Li Chen, Lei Gou, Huai-Ming Hu*, Feng Fu, Zhong-Xi Han, Hui-Ming Shu, Meng-Lin Yang, Gang-Lin Xue, Chuan-Qin Du, New Examples of Metal Coordination Architectures of 4,4’-Sulfonyldibenzoic Acid: Syntheses, Crystal Structure and Luminescence, Eur. J. Inorg. Chem. 2008, (2), 239-250.
2. Qing-Ran Wu, Xiao-Li Chen, Huai-Ming Hu*, Ting Qin, Feng Fu, Bo Zhang, Xing-Long Wu, Meng-Lin Yang, Gang-Lin Xue, Assembly of a novel Ag(I) supramolecular architecture constructed from flexible ligand containing asymmetrical tricarboxylate, Inorg. Chem. Commun. 2008, 11(1), 28-32.
3. Lei Gou, Qing-Ran Wu, Huai-Ming Hu*, Ting Qin, Gang-Lin Xue, Meng-Lin Yang, Zong-Xun Tang, An investigation of the positional isomeric effect of terpyridine derivatives: Self-assembly of novel cadmium coordination architectures driven by N-donor covlence and π???π non-covalent interactions, Polyhedron, 2008, 27(5) 1517-1528.
4. Lei Gou, Qing-Ran Wu, Huai-Ming Hu*, Gang-Lin Xue, Meng-Lin Yang, A new family of lanthanide terpyridine nitrate complexes: Solvothermal syntheses, crystal structures and luminescent properties of [Ln(pytpy)(NO3)2(OCH3)]2, Inorg. Chim. Acta, 2008, 361(7), 1922-1928.
5．Lei Gou, Li-Feng Xu, Huai-Ming Hu*, Bao-Cheng Wang, Xiao-Li Chen, Zong-Xun Tang, NiII-CdII Heterometallic Coordination Compounds Constructed from Metal-containing N,N’-Rodlike Building Block [Ni(4’-(3-pyridyl)-2,2’:6’,2”- terpyridine)2]2+ Cation Z. Anorg. Allg. Chem. 2008, 634, 1215-1220.
6. Lei Gou, Bo Zhang, Huai-Ming Hu*, Xiao-Li Chen, Bao-Cheng Wang, Qing-Ran Wu, Ting Qin, Zong-Xun Tang, Syntheses and Characterization of Two Novel CdII Coordination Polymers Derived From Pyridyl Substituted Terpyridine and Diphenate Mixed Ligands, J. Mol. Struct. 2008, doi:10.1016/j.molstruc.2008.02.010.
7. Zhong-Xi Han, Ji-Jiang Wang, Huai-Ming Hu*, Xiao-Li Chen, Qing-Ran Wu, Dong-Sheng Li, Qi-Zhen Shi, Effects of the Size of Aromatic Chelate Ligands and d10 Metal Ions on the Structures of Dicarboxylate Complexes: From Dinuclear Molecule to Helical Chains and 2D Network, J. Mol. Struct. 2008, doi:10.1016/ j.molstruc.2008.04.010
8. Xu Li-Feng, Chen Xiao-Li, Hu Huai-Ming*, Wang Bao-Cheng, Syntheses, Structures and Electrochemical Properties of Two Co-crystal Copper(II) Melamine Complexes, J. Mol. Struct. 2008, doi:10.1016/j.molstruc.2008.05.018.
9. Xiao-Ming Gao, Dong-Sheng Li*, Ji-Jiang Wang, Feng Fu, Ya-Pan Wu, Haui-Ming Hu*, Ji-Wu Wang, A novel 1D armed-polyrotaxane chain constructed from a V-shaped tetracarboxylate ligand, CrystEngComm, 2008, 10, 479-482.
10. Gang-Lin Xue, Xue-Mei Liu, Hai-Sheng Xu, Huai-Ming Hu, Feng Fu, Ji-Wu Wang, An Unusual Asymmetric Polyoxomolybdate Containing Mixed-valence Antimony and Its Derivatives: [Sb4VSb2IIIMo18O73(H2O)2]12- and {M(H2O)2 [Sb4VSb2III Mo18O73(H2O)2]2}22- (M=MnII, FeII,CuII, CoII), Inorg. Chem. 2008, 47(6), 2011-2016.
11. Xia Li, Chun-Yan Wang, Huai-Ming Hu, The first example of tetranuclear lanthanide complexes with 2-sulfobenzoate and 1,10-phenanthroline. Inorg. Chem. Commun. 2008, 11(3), 345-348.
12．Wen Yang, Ying Liu, Ganglin Xue, Huaiming Hu, Feng Fu, Jiwu Wang. A one-dimensional assembly of a Keggin tungstogermanate and sodium- pyridine-2-carboxylic acid: NaH3(C6H5N2)4[GeW12O40].7H2O. J. Coord. Chem. 2008, 61(15), 2499-2505.
13. Ji-Jiang Wang, Lei Gou, Huai-Ming Hu*, Zhong-Xi Han, Dong-Sheng Li, Gang-Lin Xue, Meng-Lin Yang, Qi-Zhen Shi, Ligand and pH-Controlled Zinc(II) Bilayer Coordination Polymers Based on Biphenyl-3,3',4,4'-tetracarboxylate, Cryst. Growth Des. 2007, 8, 1514-1521.
14. Ji-Jiang Wang, Meng-Lin Yang, Huai-Ming Hu*,Gang-Lin Xue, Dong-Sheng Li, Qi-Zhen Shi, Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3D cadmium(II) coordination polymer containing [Cd5(μ3-OH)2 (μ3-OAc)2]6+ cores, Inorg. Chem. Commun. 2007, 10, 269-272.
15. Ji-Jiang Wang, Meng-Lin Yang, Huai-Ming Hu*, Gang-Lin Xue, Dong-Sheng Li, Qi-Zhen Shi, Influence of the Size of Aromatic Chelate Ligands on the Structures of Cadmium(II) Tetracarboxylates Polymers: From 2D Layered Network to 3D Metal-Organic Framework, Z. Anorg. Allg. Chem. 2007, 633, 341-345.
16. Xiao-Li Chen, Ji-Jiang Wang, Huai-Ming Hu*, Feng Fu, Hui-Ming Shu, Meng-Lin Yang, Gang-Lin Xue, Chuan-Qin Du, Yue-Juan Yao, Hydrothermal Syntheses, Crystal Structures and Luminescence of Two Novel Metal–organic Frameworks, Z. Anorg. Allg. Chem. 2007, 633, 2053-2058.
17. Ji-Jiang Wang, Bo Zhang, Hui-Ming Shu, Chuan-Qin Du, Huai-Ming Hu*, A two-dimensional coordination polymer containing linear trinuclear copper(II) clusters. Acta Cryst. Section E: Structure Reports Online, 2007, E63(8), m2190.
18. Yue-Juan Yao, Hui-Ming Shu, Chuan-Qin Du, Huai-Ming Hu*, Bis{2-[N,N-bis (2-aminoethyl)amino]ethanaminium}nickel(II)hexacyanoferrate(II). Acta Cryst. Section E: Structure Reports Online, 2007, E63(5), m1208-m1210.
19. 姚月娟,舒慧名,杜传芹,王记江,胡怀明*，双核镉配合物{Cd2(C7H3NO5)2 (C5H5N)6?2H2O}的合成和晶体结构, 西北大学学报(自然科学版), 2007, 37, 62-65(增刊)。
20．杜传芹，舒慧明，姚月娟，王记江，胡怀明*，氧中心羧酸桥连三核铁配合物的制备及晶体结构，西北大学学报(自然科学版), 2007, 37, 66-69(增刊)。
21. Ying Liu, Bin Liu, Gang-Lin Xue, Huai-Ming Hu, Feng Fu, Ji-Wu Wang, The novel sandwich-type heterpolyoxotungstates [M2Bi2(β-B-MW9O34)2]14- (M=CoII, ZnII): β-type dimeric heterpolyanions with a transition metal as the central heteroatom and BiIII and M as linking atoms, Dalton Trans, 2007, 3634-3639.
22. Rui-Rui Cui, Hu-Lin Wang, Xin-Yu Yang, Shu-Hu Ren, Huai-Ming Hu, Feng Fu, Ji-Wu Wang, Gang-Lin Xue. Imidazole coordinated sandwich-type antimony polyoxotungstates Na9[{Na(H2O)2}3{M(C3H4N2)}3(SbW9O33)2].xH2O (M = NiII, CoII, ZnII, MnII). Chin. J. Chem. 2007, 25(2), 176-181.
23. Wang-Ting Wu, Shui-Yang He, Huai-Ming Hu, Meng-Lin Yang, Yao-Yu Wang, Qi-Zhen Shi. Crystal structure and fluorescence of the supramolecular complex [Dy(H2L)(HL)(H2O)3].0.5dipy.2H2O. J. Coord. Chem. 2007, 60(2), 125-130.
24. Yan-Xin Yu, Huai-Ming Hu, De-Qing Zhang, Zhi-Yong Wang, Dao-Ben Zhu. Two new nitronyl nitroxide radicals and their complexes with M(hfac)2 [M = Co(II), Ni(II), Mn(II)]: syntheses, crystal structures, and magnetic characterizations. Chin. J. Chem. 2007, 25(9), 1259-1266.
25. Biao Wu, Xiaojuan Huang, Jianjun Liang, Yanyan Liu, Xiao-Juan Yang, Huai-Ming Hu. Assembly of two supramolecular structures by metal complexes with a urea-based pyridyl ligand. Inorg. Chem. Commun. 2007, 10(5), 563-566.
26. Long Tang, Dong-Sheng Li, Feng Fu, Ji-Jiang Wang, Huai-Ming Hu, Yao-Yu Wang. Novel 3-D supramolecular architectures constructed from Zn2+ ions, oxybis(4-benzoate) and di(2-pyridyl)amine ligands. Chin. J. Chem. 2007, 25(11), 1641-1645.
27. Ying-Hui Ren, Ji-Rong Song, Kang-Zhen Xu, Hai-Xia Ma, Jie Huang, Ding-Wei Fu, Huai-Ming Hu. Preparation, crystal structure and theoretical calculation of N-(pyrimidin-2-yl)-N'-methoxycarbonyl-thiourea. Chin. J. Chem. 2007, 25(4), 510-514.
28. Fu Dingwei, Song Jirong, Ren Yinghui, Lu Xingqiang, Hu, Huaiming. Synthesis and crystal structure of 1-benzoyl-3-(4,6-dimethoxylpyrimidin-2-yl) thiourea. Huaxue Tongbao. 2007, 70(12), 942-947.
29. Liu Ying, Shang Junfei, Xue Ganglin, Hu Huaiming, Fu Feng, Wang Jiwu. A dimeric FeIII-substituted Keggin tungstogermanate: {GeFe2W10O38(OH)]2}14-. J. Cluster Science. 2007, 18(1), 205-216.
30. Li Baolin, Guo Jian, Zhang Xiquan, Lai Yitian, Hu Huaiming. Synthesis of 3,4,5-trimethoxy-4'-hydroxystilbene derivatives and crystal structure of ethyl {4-[(E)-2-(3,4,5-trimethoxyphenyl)vinyl]phenoxy}acetate. Z. Naturforsch. B: Chem. Sciences. 2007, 62(2), 244-248.
31. Xin-Jun Luan, Xue-Hua Cai, Yao-Yu Wang, Dong-Sheng Li, Cui-Juan Wang, Ping Liu, Huai-Ming Hu, Qi-Zhen Shi, Shie-Ming peng. An Investigation of the Self-Assembly of Neutral, Interlaced, Triple-Stranded Molecular Braids, Chem. Eur. J. 2006, 12, 6281-6289.
32. Xian-Lan Hong, Yi-Zhi Li, Huai-Ming Hu, Yi Pan, Jun-Feng Bai, Xiao-Zeng You. Synthesis, Structure, Luminescence, and Water Induced Reversible Crystal to Amorphous Transformation Properties of Lanthanide(III) Benzene-1,4-dioxyl acetates with a Three-Dimensional Framework, Cryst. Growth Des. 2006, 6, 1221-1226.
33. Wang-Ting Wu; Shui-Yang He, Huai-Ming Hu, Meng-Lin Yang; Yao-Yu Wang, Qi-Zhen Shi. Crystal structure and fluorescence properties of the supramolecule complex [Dy(H2L)(HL)(H2O)3].0.5dipy.2H2O. J. Coord. Chem. 2006, 59(16), 1785-1791.
34. 付峰，李东升，冯勇，王巧玲，王继武，胡怀明，王尧宇. 基于2,3-二羟基丁二酸新配位方式构建的新颖双U形四核铜配合物[Cu4(dhbd)2 (dpphen)4?2H2O]?8H2O. 化学学报，2006, 64(15), 1606-1610.
35. 宋纪蓉, 任莹辉, 黄洁, 马海霞, 徐抗震, 胡怀明. 4-(1,2,4-三唑-5-酮-4-基)-3-硫代脲酸乙酯的合成,晶体结构及理论计算. 化学学报, 2006, 64(13), 1334-1340.
36. Wang-Ting Wu, Feng-Ying Chen, Shui-Yang He, Huai-Ming Hu, Meng-Lin Yang, Yao-Yu Wang. Synthesis and crystal structure of the binuclear complex [Pr2(C10H8N2O4)2(C10H9N2O4)2(H2O)4].3H2O.C6H6. Chin. J. Chem. 2006, 24(5), 711-713.
37. Ying-Hui Ren, Ji-Rong Song, Jie Huang, Hai-Xia Ma, Hua-Li Wang, Huai-Ming Hu, Zhen-Yi Wen. Preparation, crystal structure and theoretical calculation of 4-(4,6-dimethylpyrimidin-2-yl)-3-thio-allophanic acid methyl ester. Chin. J. Chem. 2006, 24(2), 219-223.
38. 黄洁, 宋纪蓉, 任莹辉, 马海霞, 王花丽, 胡怀明, 文振翼. 4,6-二甲氧基-2-[甲氧脲基硫代脲基]嘧啶的合成,晶体结构和理论计算. 化学学报, 2006, 64(1), 9-16.
39. Shi Yapeng, Xue Ganglin, Hu Huaiming, Fu Feng, Wang Jiwu. Synthesis and characterization of the organoimidopolyoxomolybdates [n-Bu4N]2[Mo6O17(NAr)2] (Ar= 2-ethyl-6-methylphenyl and 2-isopropyl-6-methylphenyl). J. Coord. Chem. 2006, 59(15), 1739-1747.
40. Liu Xuemei, Xue Ganglin, Hu Huaiming, Gao Quanchang, Fu Feng, Wang Jiwu. Synthesis and crystal structure of a new charge transfer salt [NBu4]6H[Fe(C5H5)2][PMoVMo11O40]2. J. Mol. Struct. 2006, 787(1-3), 101-105.
41. Shi Yapeng, Yang Wen, Xue Ganglin, Hu Huaiming, Wang Jiwu. A novel crystal coexisting with two kinds of polyoxomolybdates: [n-Bu4N]8[Mo6O19]2[(Mo8O26)]. J. Mol. Struct. 2006, 784(1-3), 244-248.
42. Dao YongWang, Gang Liu, Bo Zheng, Jun Lu, Huai Ming Hu*. Bis[tetraaqua (1,10-phenanthroline-2N,N')cobalt(II)]1,2,4,5-benzenetetracarboxylate. Acta Cryst. Section E: Structure Reports Online. 2005, E61(5), m925-m927.
43. Bo Zheng, Gang Liu, Lei Gou, Dao-Yong Wang, Huai-Ming Hu*. A one- dimensional coordination polymer of copper(II) with 2-pyrazinecarboxylate. Acta Cryst. Section E: Structure Reports Online. 2005, E61(3), m499-m501.
44. Lei Gou, Xiong-Wei Qu, Bo Zheng, Dao-Yong Wang, Huai-Ming Hu*. (Nitrato-? O)(1,10-phenanthroline-2N,N')(picolinato-N-oxide-k2O,O')copper(II). Acta Cryst. Section E: Structure Reports Online. 2005, E61(3), m441-m442.
45. Liu, Xue-Mei; Wang, Chong-Ren; Liu, Bin; Xue, Gang-Lin; Hu, Huai-Ming; Wang, Ji-Wu; Fu, Feng. Structure and magnetic properties of pyridine coordinated sandwich-type heteropolyanion {[Na(H2O)2]3[Ni(C5H5N)]3(AsW9O33)2}9-. Chin. J. Chem. 2005, 23(10), 1412-1416.
46. Xin-Jun Luan, Yao-Yu Wang, Dong-Sheng Li, Ping Liu, Huai-Ming Hu, Qi-Zhen Shi, Shie-Ming Peng, Self Assembly of an Interlaced Triple-Stranded Molecular Braid with an Unprecedented Topology through Hydrogen-Bonding Interactions, Angew. Chem. Int. Ed. 2005, 44, 3864-3867.
47. 武望婷, 何水样, 胡怀明, 王尧宇, 史启祯. [Eu(C10H9N2O4)(C10H8N2O4) (H2O)3] ?0.5bipy ?3H2O配合物的合成,晶体结构及荧光性质. 化学学报, 2005, 63(22), 2032-2036.
48. Ying Hui Ren, Ji Rong Song, Jie Huang, Xiao Hong Sun, Huai Ming Hu. Methyl N-[4-(4,6-dimethylpyrimidin-2-ylamino)thiocarbonyl]carbamate. Acta Cryst. Section E: Structure Reports Online. 2005, E61(12), o4013-o4015.
49. Mei Shi, Fu-You Li, Tao Yi, Deng-Qing Zhang, Huai-Ming Hu, Chun-Hui Huang, Tuning the triplet energy levels of pyrazolone ligands to match the 5D0 level of Europium(III), Inorg. Chem. 2005, 44, 8929-8936.
50. Shi Yapeng, Lu Xinzhong, Fu Feng, Xue Ganglin, Hu Huaiming, Wang Jiwu. Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate [n-Bu4N]2 [Mo6O17((MeO)2C6H3N)2]. J. Chem. Crystallogr. 2005, 35(12), 1005-1010.
51. Liu Xuemei, Lu Xinzhong, Fu Feng, Liu Bin, Hu Huaiming, Gao Quanchang, Wang Jiwu, Xue Ganglin. Synthesis and crystal structure of a novel charge transfer salt, (TMT-TTF)4[HPMo12O40]. J. Mol. Struct. 2005, 751(1-3), 17-21.
52. 米春喜，胡怀明*，硫氰酸根桥连双核铜配合物[?-(SCN)Cu(dien)]2(ClO4)2 的合成,晶体结构和磁性研究, 陕西师范大学学报（自然科学版）, 2004, 32, 71-74.
53. Cao YD, Zheng QY, Chen CF, Hu HM, Huang ZT, Synthesis of a novel three-coordinate copper(I) complex: a structural mimic of the reduced form of type 1 site in copper protein, Inorg. Chem. Acta. 2004, 357(1), 316-320.
54. Xue GL, Liu B, Hu HM, Yang JH, Wang JW, Fu F, Large heteropolymetalate complexes formed from lanthanide (Y, Ce, Pr, Nd, Sm, Eu, Gd), nickel cations and cryptate [As4W40O140]28-: synthesis and structure characterization, J. Mol. Struct. 2004, 690(1-3), 95-103.
55. Li X, Zou YQ, Zheng B, Hu HM. catena-Poly[europium(III)-tri-mu-2,3- dimethoxybenzoato], Acta Cryst. 2004, C60, M197-M199.
56. Ren P, Qin JG, Chen CT, Zhang DQ, Hu HM. Solvothermal synthesis and crystal structure of an inorganic-organic hybrid compound [DAMS]2[CdI4] (DAMS= 4-dimethylaminostyryl-1-methyl-pyridinium), J. Chem. Crystallogr. 2004, 34(4), 291-294.
57. Yang XJ, Wu B, Janiak C, Sun WH, Hu HM. Second-sphere coordination of the tris(5,5'-diamino-2,2'-bipyridine)iron complex with arene-carboxylate ligands through N-H…O hydrogen bonding, Z. Anorg. Allg. Chem. 2004, 630 (11), 1564-1572.
58. 刘斌, 薛岗林, 胡怀明, 王兰英, 史启祯, 郑丽敏，忻新泉，王继武. 新型杂多阴离子[{Na2(H2O)3}Ni(H2O)VOAs4W40O140]21-的结构和表征. 化学学报，2004, 62 (13), 1222-1225.
59. Ren P, Qin JG, Zhang DQ, Hu HM. Synthesis and crystal structure of an inorganic-organic hybrid [DMAPM]+[CdI3]-: The first example of Cd2I62- dimmer. Chin. J. Struct. Chem. 2004, 23(7), 735-738.
60. Xie, Chi; Wang, Wei; Zou, Jian-Zhong; Liu, Hong-Li; Shen, Xiao-Ping; Li, Bao-Long; Hu, Huai-Ming; Xu, Zheng. Template self-assembly of cyano-bridged supramolecular complexes {[Cu(en)2][KM(CN)6]}n (M = CrIII, FeIII, CoIII). J. Coord. Chem. 2004, 57(17-18), 1519-1527.
61. Merz K, Hu HM, Rell S, Driess M. Syntheses and molecular structures of metallasiloxanes containing Zn3O4 and Zn6Si6O10 cores, Eur. J. Inorg. Chem. 2003, 51-53.
62. Lu J, Li M, Bai YJ, Hu HM, Ma HR. Synthesis and X-ray structure determination of diferrocenyl disulfide. Syn. React. Inorg. Metal-org. Chem. 2003, 33 (6): 999-1009.
63. Chen ZF, Liang H, Hu HM, Li Y, Xiong RG, You XZ. A neutral 2D nanosized molecular square grid: the first vanadium(II) coordination polymer of norfloxacin, Inorg. Chem. Commun. 2003, 241-243.
64. Liu CM, Zhang DQ, Luo JL, Wang NL, Hu HM, Zhu DB, A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)2(H2O)(ClO4). Eur. J. Inorg. Chem. 2003, (19), 3618-3622.
65. Zhang W, Hua JL, Shao P, Ren P, Qin JG, Zhang Y, Lu ZH, Hu HM, Zhang DQ. Synthesis, crystal structure, and nonlinear optical property of two new chromophores containing furan ring as a conjugation bridge. Chem Lett, 2003, 32(4), 386-387.
66. Shen XP, Li BL, Zou JZ, Hu HM, Xu Z. The first cyano-bridged heptanuclear MnIII6FeIII cluster: crystal structure and magnetic properties of [{Mn (salen).H2O.6Fe(CN)6}[Fe(CN)6].6H2O. J. Mol. Struct. 2003, 657 (1-3), 325-331.
67. Jia CY, Zhang DQ, Xu Y, Xu W, Hu HM, Zhu DB. New TTF derivatives with pyridine groups: synthesis, electrochemical studies, crystal structure and formation of conducting LB films. Synthetic Metals, 2003, 132, 249-255.
68. 瞿雄伟, 刘刚, 张留成, 李林, 胡怀明*. 五水合3,5-二羧基吡啶钴(II)配合物的制备及其晶体结构. 高等学校化学学报，2003, 24(6), 983-985.
69. 路军, 李明, 白银娟, 胡怀明. S二硫二茂铁的合成及其晶体结构. 有机化学. 2003, 23 (3), 277-280.
70. 王虎林， 薛岗林， 徐媛， 王兰英， 王文亮， 胡怀民. 2,3-二苯基-1,4,6-三氮杂二环[3.3.1]-2-壬烯单盐酸盐的合成及晶体结构. 有机化学，2003, 23(7), 710-713.
71. Liu CM, Gao S, Hu HM, Jin XL, Kou, HZ. Hydrothermal syntheses and crystal structures of two-dimensional (2D) layerd vanadium oxide complexes: M(bipy)(H2O)V2O6 (M=Ni, Co, bipy=bipyridine) and [Ni(bipy)2V6O17], J. Chem. Soc., Dalton Trans. 2002, 598-601.
72. Sun WH, Shao CX, Chen Y, Hu HM, Sheldon RA, Wang HG, Leng XB and Jin XL, Controllable supramolecular assembly by pi-pi interactions: Cobalt(II) and copper(II) complexes with benzimidazole derivatives. Organometallics, 2002, 21, 4350-4355.
73. Liu CM, Zhang DQ, Xiong M, Dai MQ, Hu HM, Zhu DB. Hydrothermal synthesis, crystal structures and magnetic properties of two bimetallic cage cluster vanadate complexes [Co(phen)2]2V4O12 and [Co(2,2’-bipy)2V4O12. J. Coord. Chem. 2002, 55, 1327-1335.
74. Sun WH, Li ZL, Hu HM, Wu B, Yang HB, Zhu N, Leng XB, Wang HG. Synthesis and characterization of novel nickel (II) complexes bearing N, P ligands and their catalytic activity in ethylene oligomerization. New J Chem. 2002, 26, 1474-1478.
75. Liu CM, Zhang DQ, Qin AJ, Ye C, Hu HM, Zhu DB. A novel nickel (II) complex adopting a cis-configuration: solvothermal synthesis and crystal structure of [NiL2(H2O)4] (L=1,4-dihydropyrazine-2,3-dione-5,6-dicarboxylate). Eur. J. Inorg. Chem. 2002, 1595-1598.
76. Shen XP, Zou JZ, Li BL, Hu HM, Xu Z. A novel self-assembled supramolecular complex {[Cu(II)(en)2?H2O][Cu(I)2(CN)4]}n with honeycomb-like structure and its adsorption properties. Chin. J. Chem. 2002, 20, 1472-1476.
77. Zhang DQ, Ding L, Xu W, Hu HM, Zhu DB, Huang YH, Fang DC. 1D silver (I) complex of nitronyl nitroxide with strong spin-spin interaction through silver(I) ion. Chem. Commun. 2002, 44-45.
78. Jia CY, Zhang DQ, Liu CM, Xu W, Hu HM, Zhu DB. Novel silver(I) complexes derived from tetrakis(methylthio)tetrathiafulvalene and bis(ethylenedithio) tetrathiafulvalene with 3D and 1D structures. New J Chem. 2002, 490-194.
79. Liu CM, Gao S, Hu HM, Wang ZM. A novel bimetallic cage complex constructed from six V4Co pentatomic rings: hydrothermal synthesis and crystal structure of [2,2’-Py2NH]2Co]3V8O23. Chem. Commun. 2001, 1636-1637.
80. Zou YQ, Li X, Li Y, Hu HM. Tetrakis(?-2,3-dimethoxybenzoato)bis[(2,2’-bi pyridine)(2,3-dimethoxybenzoato)lanthanum(III)]. Acta Cryst. 2001, C57, 1048- 1050.
81. Long DL, Cui CP, Hu HM, Chen JT, Ji ZP, Zhang YD, Huang JS. Non-linear optical absorption of [{Ni(mnt)2}2]2- and its unique counter ion, a disodium triple-decker dication [Na-2(benzo-15-crown-5)3 (H2O)2]2+. Inorg. Chem. Acta, 2000,298,125-131.
82. Wang QH, Long DL, Hu HM, Cui Y, Huang JS. Syntheses, crystal structures and electronic spectra of mixed-ligand zinc(II) complexes with diimines and dithiolates. J. Coord. Chem. 2000, 49(3), 201-209.
83. Lin SH, Wang ZQ, Zhang BH, Hu HM, Huang JS. Crystal structure of tris(2,2’-bipyridine)nickel(II) tetrachlorozincate, 结构化学, 2000, 19(2), 95-98.
84. Hu HM, Huang XY, Sun HS, Long DL, Huang JS, You XZ. Synthesis, crystal structure and magnetic properties of a thiocyanate bridged one-dimensional chain copper(II) complex: {[(232-tet)Cu(NCS)](ClO4)}n. J. Coord. Chem. 1999, 47(4), 531-540.
85. Cai H, Hu HM, Chen WZ, Zhu HG, You XZ. A novel three-dimensional framework: Self-assembly of AgNO3 and pyrimidine. Chem. Lett. 1999, (3), 221-222.
86. Long DL, Hu HM, Chen JT and Huang JS. [La(NO3)2(Ph3PO)4]2 [Ni(C4N2S2)2]. 2CH3OH, Acat Cryst. 1999, C55(10), 1662-1664.
87. Zhu HG, Yu Z, You XZ, Hu HM, Huang XY. The crystal and molecular structure of bis(melamine) silver(I) perchlorate Ag(C3H6N6)2ClO4. J. Chem. Crystallogr. 1999, 29(2), 239-242.
88. Sun HS, Zhao Q, Liu YJ, Hu HM, You XZ, Zhou ZY. Synthesis and characterization of complexes of Me3M (M = Al, Ga) or Et3In with bis(dimethylamino)-2-propanol. X-ray crystal structure of the [Me2GaOCH(CH2NMe2)2]2 dimer. J. Coord. Chem. 1999, 47(3), 459-465.
89. Long DL, Hu HM, Chen JT, Huang JS. [Ni{(CH3)2SO}6]I-4, a redetermination and reinterpretation. ACTA CRYST, 1999, C55(3), 339-341.
90. Hu HM, Long DL, Zeng HY, Cheng WD & Huang JS, A redetermination of bis(2-aminomethylpyridine)diperchloratocopper(II), Acta Cryst. 1999, C55(5). IUC9900049.
91. Cai, Hu; Hu, Huai-Ming; Chen, Wan-Zhi; Xu, Yan; You, Xiao-Zeng. 1,4-Bis(4H-1,2,4-triazol-4-yl)benzene monohydrate. Acta Cryst. Section C: Crystal Structure Communications. 1999, C55(8), IUC9900082.
92. Hu HM, Sun HS, Zhao Q, Yu Z, Huang XY, You XZ. Synthesis, crystal structure and magnetic properties of an imidazolate bridged dinuclear nickel(II) complex: ?-(Im)-[(232-TET)Ni]2(ClO4)3. J. Coord. Chem. 1998, 43(4), 361-369.
93. Hu HM, Sun HS, Duan CY, Zhao Q, You XZ, Zhou ZY, Zhou XG, (Carbonato-O,O') bis(1,2-thanediamine-N,N')cobalt(III) perchlorate. Acta Cryst. 1997, C53(8), 1014-1015.
94. Hu HM, Sun HS, Huang XY, Chen XH, Liu YJ, You XZ, meso-5,5,7,12,12,14-hexa- methyl-1,4,8,11-tetraazacyclotetradecane dihydroperchlorate monohydrate, ACTA CRYST, 1997, C53(5), 588-590.
95. Hu HM, Sun HS, Chen XH, Zhao Q, Pan Y, Huang XY, You XZ. (Diethylenetriamine) (imidazole)(thiocyanato)copper(II) perchlorate. Acta Cryst. 1997, C53(3),276-278.
96. Yu SY, Wang QM, Wu B, Wu XT, Hu HM, Wang LF, Wu AX. Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)].KSCN.CH3CN.3H2O (L is a deprotonated phenol-based N8O3 cryptand), Polyhedron, 1997, 16(2), 321-325.
97. 胡怀明， 孙红随， 高忆慈， 彭周人. 三甲基胺氧化物希土配合物的振动光谱和配位结构研究. 无机化学学报, 1997, 13(2), 124-127.
98. 陈景文， 廖宜勇， 冯流， 黄庆国， 韩朔睽， 王连生， 胡怀明，陆国元， 赵焘南. 应用量子化学MNDO方法预测取代氮杂环类化合物的生物活性, 科学通报, 1997, 42(2), 157-159.
99. Chen JW, Huang QG, Wang LS, Hu HM, Zhang Z. Using AM1 Hamiltonian and factor analysis in prediction of partition properties for phenylthio, phenylsulfinyl and phenylsulfonyl acetates. CHEMOSPHERE, 1996, 33(12), 2565-2575.
100. Hu HM, Sun HS, You XZ, Huang XY. (Acetato-O)(meso-5,5,7,12,12,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane-N,N',N'',N''')zinc(II) perchlorate mono- hydrate, ACTA CRYST, 1996, C52(8), 1946-1948.
101. Chen JW, Feng L, Liao YY, Wang LS, Hu HM. Using AM1 Hamiltonian in quantitative structure-properties relationship studies of alkyl (1-phenylsulfonyl) cycloalkane-carboxylates. Chemosphere. 1996, 33(3), 537-546.
部门：物理化学学部 出生年月：1964-5-22
籍贯：陕西府谷 职称：教授/博士生导师
邮箱：ChemHu1@nwu.edu.cn 电话： 029－88303331(O)
研究方向： 结构化学；晶体工程；发光材料化学
简 介
胡怀明，男，博士，教授，博士生导师，生于1964年5月。现任西北大学教授，中国晶体学会小分子委员会委员,陕西省分析测试协会理事。1981.9~1985.7：在延安大学化学系化学专业学习，获学士学位。1985.9~1988.7：在兰州大学化学系物理化学专业读硕士研究生，获硕士学位。1988.8~1994.2：在陕西师范大学化学系任助教及讲师。1994.3~1997.7：在南京大学配位化学研究所做博士研究生，获博士学位。1997.9~1999.5：在中国科学院福建物质结构研究所做博士后，主要研究大环配合物的合成和结构。1999.5~2000.5：在德国鲁尔波鸿大学（Ruhr-Universit?t Bochum）无机化学I系做博士后，主要研究金属硅氧烷的合成和结构。2000.5~2003.9：在中国科学院化学研究所任副研究员，主要从事晶体结构分析和化学结晶学研究。2002.5~2003.6：在英国伯明翰大学(University of Birmingham)化学学院做访问研究，主要研究稀土配合物的结构和发光性质。目前主要从事稀土和过渡金属配合物的结构化学和发光性能研究。稀土离子具有线状光谱,长寿命和大斯托克斯位移的独特光学性质，在生物体系的荧光免疫分析,临床诊断,显示器件,发光传感器,激光材料和远程通讯等领域具有潜在的应用。我们设计合成出能够对紫外光有强吸收的,能够把吸收的能量有效传递给稀土离子,并能保护稀土离子的激发态不进行非辐射去活的有机配体，然后自组装出发光性能优异的化合物。主持教育部留学回国人员科研启动基金，人事部留学回国人员基金，陕西省自然科学研究计划项目（2004B09），陕西省教育厅自然科学专项(07JK385)，国家自然科学基金(20573083, 20873098)等。在Angew. Chem. Int. Ed.,Chem. Eur. J.,Chem. Commun.,J. Chem. Soc.，Dalton Trans.,Inorg. Chem.,New J. Chem.,Organometallics,Eur. J. Inorg. Chem.,Polyhedron,Inorg. Chim. Acta等SCI期刊上发表学术论文100多篇。
一,学历：
1981.9-1985.7 延安大学化学系化学专业学习，获学士学位。
1985.9-1988.7 兰州大学化学系物理化学专业学习，获硕士学位。
1994.3-1997.7南京大学配位化学研究所无机化学专业学习，获博士学位。
二,工作经历：
1988.8-1994.2陕西师范大学化学系助教及讲师。
1997.9-1999.5中科院福建物质结构研究所做博士后研究。
1999.5-2000.5德国鲁尔波鸿大学(Ruhr-Universit?t Bochum)做博士后研究。
2000.5-2003.9中国科学院化学研究所X射线衍射室副研究员，负责X射线衍射工作和相关的研究工作。其中，2002.5-2003.6获英国皇家化学会基金资助,在英国伯明翰大学(Birmingham University)做访问研究。
2003.10- 西北大学教授，从事结构化学和化学结晶学的教学和科研工作。
三．主持的在研项目：
1. 国家自然科学基金(20573083)
项目的名称: 过渡金属配位结构单元调控镧系离子近红外发光的研究
经费来源：国家自然科学基金委
2. 国家自然科学基金 (20873098)
项目的名称: beta-二酮基双极配体的间隔臂调控镧系配合物近红外发光性能的研究
经费来源：国家自然科学基金委
3. 陕西省教育厅自然科学专项 (07JK385)
项目的名称: 稀土双β-二酮配合物的合成,结构和发光性质研究
经费来源：陕西省教育厅
四．发表论文：
1. Xiao-Li Chen, Lei Gou, Huai-Ming Hu*, Feng Fu, Zhong-Xi Han, Hui-Ming Shu, Meng-Lin Yang, Gang-Lin Xue, Chuan-Qin Du, New Examples of Metal Coordination Architectures of 4,4’-Sulfonyldibenzoic Acid: Syntheses, Crystal Structure and Luminescence, Eur. J. Inorg. Chem. 2008, (2), 239-250.
2. Qing-Ran Wu, Xiao-Li Chen, Huai-Ming Hu*, Ting Qin, Feng Fu, Bo Zhang, Xing-Long Wu, Meng-Lin Yang, Gang-Lin Xue, Assembly of a novel Ag(I) supramolecular architecture constructed from flexible ligand containing asymmetrical tricarboxylate, Inorg. Chem. Commun. 2008, 11(1), 28-32.
3. Lei Gou, Qing-Ran Wu, Huai-Ming Hu*, Ting Qin, Gang-Lin Xue, Meng-Lin Yang, Zong-Xun Tang, An investigation of the positional isomeric effect of terpyridine derivatives: Self-assembly of novel cadmium coordination architectures driven by N-donor covlence and π???π non-covalent interactions, Polyhedron, 2008, 27(5) 1517-1528.
4. Lei Gou, Qing-Ran Wu, Huai-Ming Hu*, Gang-Lin Xue, Meng-Lin Yang, A new family of lanthanide terpyridine nitrate complexes: Solvothermal syntheses, crystal structures and luminescent properties of [Ln(pytpy)(NO3)2(OCH3)]2, Inorg. Chim. Acta, 2008, 361(7), 1922-1928.
5．Lei Gou, Li-Feng Xu, Huai-Ming Hu*, Bao-Cheng Wang, Xiao-Li Chen, Zong-Xun Tang, NiII-CdII Heterometallic Coordination Compounds Constructed from Metal-containing N,N’-Rodlike Building Block [Ni(4’-(3-pyridyl)-2,2’:6’,2”- terpyridine)2]2+ Cation Z. Anorg. Allg. Chem. 2008, 634, 1215-1220.
6. Lei Gou, Bo Zhang, Huai-Ming Hu*, Xiao-Li Chen, Bao-Cheng Wang, Qing-Ran Wu, Ting Qin, Zong-Xun Tang, Syntheses and Characterization of Two Novel CdII Coordination Polymers Derived From Pyridyl Substituted Terpyridine and Diphenate Mixed Ligands, J. Mol. Struct. 2008, doi:10.1016/j.molstruc.2008.02.010.
7. Zhong-Xi Han, Ji-Jiang Wang, Huai-Ming Hu*, Xiao-Li Chen, Qing-Ran Wu, Dong-Sheng Li, Qi-Zhen Shi, Effects of the Size of Aromatic Chelate Ligands and d10 Metal Ions on the Structures of Dicarboxylate Complexes: From Dinuclear Molecule to Helical Chains and 2D Network, J. Mol. Struct. 2008, doi:10.1016/ j.molstruc.2008.04.010
8. Xu Li-Feng, Chen Xiao-Li, Hu Huai-Ming*, Wang Bao-Cheng, Syntheses, Structures and Electrochemical Properties of Two Co-crystal Copper(II) Melamine Complexes, J. Mol. Struct. 2008, doi:10.1016/j.molstruc.2008.05.018.
9. Xiao-Ming Gao, Dong-Sheng Li*, Ji-Jiang Wang, Feng Fu, Ya-Pan Wu, Haui-Ming Hu*, Ji-Wu Wang, A novel 1D armed-polyrotaxane chain constructed from a V-shaped tetracarboxylate ligand, CrystEngComm, 2008, 10, 479-482.
10. Gang-Lin Xue, Xue-Mei Liu, Hai-Sheng Xu, Huai-Ming Hu, Feng Fu, Ji-Wu Wang, An Unusual Asymmetric Polyoxomolybdate Containing Mixed-valence Antimony and Its Derivatives: [Sb4VSb2IIIMo18O73(H2O)2]12- and {M(H2O)2 [Sb4VSb2III Mo18O73(H2O)2]2}22- (M=MnII, FeII,CuII, CoII), Inorg. Chem. 2008, 47(6), 2011-2016.
11. Xia Li, Chun-Yan Wang, Huai-Ming Hu, The first example of tetranuclear lanthanide complexes with 2-sulfobenzoate and 1,10-phenanthroline. Inorg. Chem. Commun. 2008, 11(3), 345-348.
12．Wen Yang, Ying Liu, Ganglin Xue, Huaiming Hu, Feng Fu, Jiwu Wang. A one-dimensional assembly of a Keggin tungstogermanate and sodium- pyridine-2-carboxylic acid: NaH3(C6H5N2)4[GeW12O40].7H2O. J. Coord. Chem. 2008, 61(15), 2499-2505.
13. Ji-Jiang Wang, Lei Gou, Huai-Ming Hu*, Zhong-Xi Han, Dong-Sheng Li, Gang-Lin Xue, Meng-Lin Yang, Qi-Zhen Shi, Ligand and pH-Controlled Zinc(II) Bilayer Coordination Polymers Based on Biphenyl-3,3',4,4'-tetracarboxylate, Cryst. Growth Des. 2007, 8, 1514-1521.
14. Ji-Jiang Wang, Meng-Lin Yang, Huai-Ming Hu*,Gang-Lin Xue, Dong-Sheng Li, Qi-Zhen Shi, Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3D cadmium(II) coordination polymer containing [Cd5(μ3-OH)2 (μ3-OAc)2]6+ cores, Inorg. Chem. Commun. 2007, 10, 269-272.
15. Ji-Jiang Wang, Meng-Lin Yang, Huai-Ming Hu*, Gang-Lin Xue, Dong-Sheng Li, Qi-Zhen Shi, Influence of the Size of Aromatic Chelate Ligands on the Structures of Cadmium(II) Tetracarboxylates Polymers: From 2D Layered Network to 3D Metal-Organic Framework, Z. Anorg. Allg. Chem. 2007, 633, 341-345.
16. Xiao-Li Chen, Ji-Jiang Wang, Huai-Ming Hu*, Feng Fu, Hui-Ming Shu, Meng-Lin Yang, Gang-Lin Xue, Chuan-Qin Du, Yue-Juan Yao, Hydrothermal Syntheses, Crystal Structures and Luminescence of Two Novel Metal–organic Frameworks, Z. Anorg. Allg. Chem. 2007, 633, 2053-2058.
17. Ji-Jiang Wang, Bo Zhang, Hui-Ming Shu, Chuan-Qin Du, Huai-Ming Hu*, A two-dimensional coordination polymer containing linear trinuclear copper(II) clusters. Acta Cryst. Section E: Structure Reports Online, 2007, E63(8), m2190.
18. Yue-Juan Yao, Hui-Ming Shu, Chuan-Qin Du, Huai-Ming Hu*, Bis{2-[N,N-bis (2-aminoethyl)amino]ethanaminium}nickel(II)hexacyanoferrate(II). Acta Cryst. Section E: Structure Reports Online, 2007, E63(5), m1208-m1210.
19. 姚月娟,舒慧名,杜传芹,王记江,胡怀明*，双核镉配合物{Cd2(C7H3NO5)2 (C5H5N)6?2H2O}的合成和晶体结构, 西北大学学报(自然科学版), 2007, 37, 62-65(增刊)。
20．杜传芹，舒慧明，姚月娟，王记江，胡怀明*，氧中心羧酸桥连三核铁配合物的制备及晶体结构，西北大学学报(自然科学版), 2007, 37, 66-69(增刊)。
21. Ying Liu, Bin Liu, Gang-Lin Xue, Huai-Ming Hu, Feng Fu, Ji-Wu Wang, The novel sandwich-type heterpolyoxotungstates [M2Bi2(β-B-MW9O34)2]14- (M=CoII, ZnII): β-type dimeric heterpolyanions with a transition metal as the central heteroatom and BiIII and M as linking atoms, Dalton Trans, 2007, 3634-3639.
22. Rui-Rui Cui, Hu-Lin Wang, Xin-Yu Yang, Shu-Hu Ren, Huai-Ming Hu, Feng Fu, Ji-Wu Wang, Gang-Lin Xue. Imidazole coordinated sandwich-type antimony polyoxotungstates Na9[{Na(H2O)2}3{M(C3H4N2)}3(SbW9O33)2].xH2O (M = NiII, CoII, ZnII, MnII). Chin. J. Chem. 2007, 25(2), 176-181.
23. Wang-Ting Wu, Shui-Yang He, Huai-Ming Hu, Meng-Lin Yang, Yao-Yu Wang, Qi-Zhen Shi. Crystal structure and fluorescence of the supramolecular complex [Dy(H2L)(HL)(H2O)3].0.5dipy.2H2O. J. Coord. Chem. 2007, 60(2), 125-130.
24. Yan-Xin Yu, Huai-Ming Hu, De-Qing Zhang, Zhi-Yong Wang, Dao-Ben Zhu. Two new nitronyl nitroxide radicals and their complexes with M(hfac)2 [M = Co(II), Ni(II), Mn(II)]: syntheses, crystal structures, and magnetic characterizations. Chin. J. Chem. 2007, 25(9), 1259-1266.
25. Biao Wu, Xiaojuan Huang, Jianjun Liang, Yanyan Liu, Xiao-Juan Yang, Huai-Ming Hu. Assembly of two supramolecular structures by metal complexes with a urea-based pyridyl ligand. Inorg. Chem. Commun. 2007, 10(5), 563-566.
26. Long Tang, Dong-Sheng Li, Feng Fu, Ji-Jiang Wang, Huai-Ming Hu, Yao-Yu Wang. Novel 3-D supramolecular architectures constructed from Zn2+ ions, oxybis(4-benzoate) and di(2-pyridyl)amine ligands. Chin. J. Chem. 2007, 25(11), 1641-1645.
27. Ying-Hui Ren, Ji-Rong Song, Kang-Zhen Xu, Hai-Xia Ma, Jie Huang, Ding-Wei Fu, Huai-Ming Hu. Preparation, crystal structure and theoretical calculation of N-(pyrimidin-2-yl)-N'-methoxycarbonyl-thiourea. Chin. J. Chem. 2007, 25(4), 510-514.
28. Fu Dingwei, Song Jirong, Ren Yinghui, Lu Xingqiang, Hu, Huaiming. Synthesis and crystal structure of 1-benzoyl-3-(4,6-dimethoxylpyrimidin-2-yl) thiourea. Huaxue Tongbao. 2007, 70(12), 942-947.
29. Liu Ying, Shang Junfei, Xue Ganglin, Hu Huaiming, Fu Feng, Wang Jiwu. A dimeric FeIII-substituted Keggin tungstogermanate: {GeFe2W10O38(OH)]2}14-. J. Cluster Science. 2007, 18(1), 205-216.
30. Li Baolin, Guo Jian, Zhang Xiquan, Lai Yitian, Hu Huaiming. Synthesis of 3,4,5-trimethoxy-4'-hydroxystilbene derivatives and crystal structure of ethyl {4-[(E)-2-(3,4,5-trimethoxyphenyl)vinyl]phenoxy}acetate. Z. Naturforsch. B: Chem. Sciences. 2007, 62(2), 244-248.
31. Xin-Jun Luan, Xue-Hua Cai, Yao-Yu Wang, Dong-Sheng Li, Cui-Juan Wang, Ping Liu, Huai-Ming Hu, Qi-Zhen Shi, Shie-Ming peng. An Investigation of the Self-Assembly of Neutral, Interlaced, Triple-Stranded Molecular Braids, Chem. Eur. J. 2006, 12, 6281-6289.
32. Xian-Lan Hong, Yi-Zhi Li, Huai-Ming Hu, Yi Pan, Jun-Feng Bai, Xiao-Zeng You. Synthesis, Structure, Luminescence, and Water Induced Reversible Crystal to Amorphous Transformation Properties of Lanthanide(III) Benzene-1,4-dioxyl acetates with a Three-Dimensional Framework, Cryst. Growth Des. 2006, 6, 1221-1226.
33. Wang-Ting Wu; Shui-Yang He, Huai-Ming Hu, Meng-Lin Yang; Yao-Yu Wang, Qi-Zhen Shi. Crystal structure and fluorescence properties of the supramolecule complex [Dy(H2L)(HL)(H2O)3].0.5dipy.2H2O. J. Coord. Chem. 2006, 59(16), 1785-1791.
34. 付峰，李东升，冯勇，王巧玲，王继武，胡怀明，王尧宇. 基于2,3-二羟基丁二酸新配位方式构建的新颖双U形四核铜配合物[Cu4(dhbd)2 (dpphen)4?2H2O]?8H2O. 化学学报，2006, 64(15), 1606-1610.
35. 宋纪蓉, 任莹辉, 黄洁, 马海霞, 徐抗震, 胡怀明. 4-(1,2,4-三唑-5-酮-4-基)-3-硫代脲酸乙酯的合成,晶体结构及理论计算. 化学学报, 2006, 64(13), 1334-1340.
36. Wang-Ting Wu, Feng-Ying Chen, Shui-Yang He, Huai-Ming Hu, Meng-Lin Yang, Yao-Yu Wang. Synthesis and crystal structure of the binuclear complex [Pr2(C10H8N2O4)2(C10H9N2O4)2(H2O)4].3H2O.C6H6. Chin. J. Chem. 2006, 24(5), 711-713.
37. Ying-Hui Ren, Ji-Rong Song, Jie Huang, Hai-Xia Ma, Hua-Li Wang, Huai-Ming Hu, Zhen-Yi Wen. Preparation, crystal structure and theoretical calculation of 4-(4,6-dimethylpyrimidin-2-yl)-3-thio-allophanic acid methyl ester. Chin. J. Chem. 2006, 24(2), 219-223.
38. 黄洁, 宋纪蓉, 任莹辉, 马海霞, 王花丽, 胡怀明, 文振翼. 4,6-二甲氧基-2-[甲氧脲基硫代脲基]嘧啶的合成,晶体结构和理论计算. 化学学报, 2006, 64(1), 9-16.
39. Shi Yapeng, Xue Ganglin, Hu Huaiming, Fu Feng, Wang Jiwu. Synthesis and characterization of the organoimidopolyoxomolybdates [n-Bu4N]2[Mo6O17(NAr)2] (Ar= 2-ethyl-6-methylphenyl and 2-isopropyl-6-methylphenyl). J. Coord. Chem. 2006, 59(15), 1739-1747.
40. Liu Xuemei, Xue Ganglin, Hu Huaiming, Gao Quanchang, Fu Feng, Wang Jiwu. Synthesis and crystal structure of a new charge transfer salt [NBu4]6H[Fe(C5H5)2][PMoVMo11O40]2. J. Mol. Struct. 2006, 787(1-3), 101-105.
41. Shi Yapeng, Yang Wen, Xue Ganglin, Hu Huaiming, Wang Jiwu. A novel crystal coexisting with two kinds of polyoxomolybdates: [n-Bu4N]8[Mo6O19]2[(Mo8O26)]. J. Mol. Struct. 2006, 784(1-3), 244-248.
42. Dao YongWang, Gang Liu, Bo Zheng, Jun Lu, Huai Ming Hu*. Bis[tetraaqua (1,10-phenanthroline-2N,N')cobalt(II)]1,2,4,5-benzenetetracarboxylate. Acta Cryst. Section E: Structure Reports Online. 2005, E61(5), m925-m927.
43. Bo Zheng, Gang Liu, Lei Gou, Dao-Yong Wang, Huai-Ming Hu*. A one- dimensional coordination polymer of copper(II) with 2-pyrazinecarboxylate. Acta Cryst. Section E: Structure Reports Online. 2005, E61(3), m499-m501.
44. Lei Gou, Xiong-Wei Qu, Bo Zheng, Dao-Yong Wang, Huai-Ming Hu*. (Nitrato-? O)(1,10-phenanthroline-2N,N')(picolinato-N-oxide-k2O,O')copper(II). Acta Cryst. Section E: Structure Reports Online. 2005, E61(3), m441-m442.
45. Liu, Xue-Mei; Wang, Chong-Ren; Liu, Bin; Xue, Gang-Lin; Hu, Huai-Ming; Wang, Ji-Wu; Fu, Feng. Structure and magnetic properties of pyridine coordinated sandwich-type heteropolyanion {[Na(H2O)2]3[Ni(C5H5N)]3(AsW9O33)2}9-. Chin. J. Chem. 2005, 23(10), 1412-1416.
46. Xin-Jun Luan, Yao-Yu Wang, Dong-Sheng Li, Ping Liu, Huai-Ming Hu, Qi-Zhen Shi, Shie-Ming Peng, Self Assembly of an Interlaced Triple-Stranded Molecular Braid with an Unprecedented Topology through Hydrogen-Bonding Interactions, Angew. Chem. Int. Ed. 2005, 44, 3864-3867.
47. 武望婷, 何水样, 胡怀明, 王尧宇, 史启祯. [Eu(C10H9N2O4)(C10H8N2O4) (H2O)3] ?0.5bipy ?3H2O配合物的合成,晶体结构及荧光性质. 化学学报, 2005, 63(22), 2032-2036.
48. Ying Hui Ren, Ji Rong Song, Jie Huang, Xiao Hong Sun, Huai Ming Hu. Methyl N-[4-(4,6-dimethylpyrimidin-2-ylamino)thiocarbonyl]carbamate. Acta Cryst. Section E: Structure Reports Online. 2005, E61(12), o4013-o4015.
49. Mei Shi, Fu-You Li, Tao Yi, Deng-Qing Zhang, Huai-Ming Hu, Chun-Hui Huang, Tuning the triplet energy levels of pyrazolone ligands to match the 5D0 level of Europium(III), Inorg. Chem. 2005, 44, 8929-8936.
50. Shi Yapeng, Lu Xinzhong, Fu Feng, Xue Ganglin, Hu Huaiming, Wang Jiwu. Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate [n-Bu4N]2 [Mo6O17((MeO)2C6H3N)2]. J. Chem. Crystallogr. 2005, 35(12), 1005-1010.
51. Liu Xuemei, Lu Xinzhong, Fu Feng, Liu Bin, Hu Huaiming, Gao Quanchang, Wang Jiwu, Xue Ganglin. Synthesis and crystal structure of a novel charge transfer salt, (TMT-TTF)4[HPMo12O40]. J. Mol. Struct. 2005, 751(1-3), 17-21.
52. 米春喜，胡怀明*，硫氰酸根桥连双核铜配合物[?-(SCN)Cu(dien)]2(ClO4)2 的合成,晶体结构和磁性研究, 陕西师范大学学报（自然科学版）, 2004, 32, 71-74.
53. Cao YD, Zheng QY, Chen CF, Hu HM, Huang ZT, Synthesis of a novel three-coordinate copper(I) complex: a structural mimic of the reduced form of type 1 site in copper protein, Inorg. Chem. Acta. 2004, 357(1), 316-320.
54. Xue GL, Liu B, Hu HM, Yang JH, Wang JW, Fu F, Large heteropolymetalate complexes formed from lanthanide (Y, Ce, Pr, Nd, Sm, Eu, Gd), nickel cations and cryptate [As4W40O140]28-: synthesis and structure characterization, J. Mol. Struct. 2004, 690(1-3), 95-103.
55. Li X, Zou YQ, Zheng B, Hu HM. catena-Poly[europium(III)-tri-mu-2,3- dimethoxybenzoato], Acta Cryst. 2004, C60, M197-M199.
56. Ren P, Qin JG, Chen CT, Zhang DQ, Hu HM. Solvothermal synthesis and crystal structure of an inorganic-organic hybrid compound [DAMS]2[CdI4] (DAMS= 4-dimethylaminostyryl-1-methyl-pyridinium), J. Chem. Crystallogr. 2004, 34(4), 291-294.
57. Yang XJ, Wu B, Janiak C, Sun WH, Hu HM. Second-sphere coordination of the tris(5,5'-diamino-2,2'-bipyridine)iron complex with arene-carboxylate ligands through N-H…O hydrogen bonding, Z. Anorg. Allg. Chem. 2004, 630 (11), 1564-1572.
58. 刘斌, 薛岗林, 胡怀明, 王兰英, 史启祯, 郑丽敏，忻新泉，王继武. 新型杂多阴离子[{Na2(H2O)3}Ni(H2O)VOAs4W40O140]21-的结构和表征. 化学学报，2004, 62 (13), 1222-1225.
59. Ren P, Qin JG, Zhang DQ, Hu HM. Synthesis and crystal structure of an inorganic-organic hybrid [DMAPM]+[CdI3]-: The first example of Cd2I62- dimmer. Chin. J. Struct. Chem. 2004, 23(7), 735-738.
60. Xie, Chi; Wang, Wei; Zou, Jian-Zhong; Liu, Hong-Li; Shen, Xiao-Ping; Li, Bao-Long; Hu, Huai-Ming; Xu, Zheng. Template self-assembly of cyano-bridged supramolecular complexes {[Cu(en)2][KM(CN)6]}n (M = CrIII, FeIII, CoIII). J. Coord. Chem. 2004, 57(17-18), 1519-1527.
61. Merz K, Hu HM, Rell S, Driess M. Syntheses and molecular structures of metallasiloxanes containing Zn3O4 and Zn6Si6O10 cores, Eur. J. Inorg. Chem. 2003, 51-53.
62. Lu J, Li M, Bai YJ, Hu HM, Ma HR. Synthesis and X-ray structure determination of diferrocenyl disulfide. Syn. React. Inorg. Metal-org. Chem. 2003, 33 (6): 999-1009.
63. Chen ZF, Liang H, Hu HM, Li Y, Xiong RG, You XZ. A neutral 2D nanosized molecular square grid: the first vanadium(II) coordination polymer of norfloxacin, Inorg. Chem. Commun. 2003, 241-243.
64. Liu CM, Zhang DQ, Luo JL, Wang NL, Hu HM, Zhu DB, A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)2(H2O)(ClO4). Eur. J. Inorg. Chem. 2003, (19), 3618-3622.
65. Zhang W, Hua JL, Shao P, Ren P, Qin JG, Zhang Y, Lu ZH, Hu HM, Zhang DQ. Synthesis, crystal structure, and nonlinear optical property of two new chromophores containing furan ring as a conjugation bridge. Chem Lett, 2003, 32(4), 386-387.
66. Shen XP, Li BL, Zou JZ, Hu HM, Xu Z. The first cyano-bridged heptanuclear MnIII6FeIII cluster: crystal structure and magnetic properties of [{Mn (salen).H2O.6Fe(CN)6}[Fe(CN)6].6H2O. J. Mol. Struct. 2003, 657 (1-3), 325-331.
67. Jia CY, Zhang DQ, Xu Y, Xu W, Hu HM, Zhu DB. New TTF derivatives with pyridine groups: synthesis, electrochemical studies, crystal structure and formation of conducting LB films. Synthetic Metals, 2003, 132, 249-255.
68. 瞿雄伟, 刘刚, 张留成, 李林, 胡怀明*. 五水合3,5-二羧基吡啶钴(II)配合物的制备及其晶体结构. 高等学校化学学报，2003, 24(6), 983-985.
69. 路军, 李明, 白银娟, 胡怀明. S二硫二茂铁的合成及其晶体结构. 有机化学. 2003, 23 (3), 277-280.
70. 王虎林， 薛岗林， 徐媛， 王兰英， 王文亮， 胡怀民. 2,3-二苯基-1,4,6-三氮杂二环[3.3.1]-2-壬烯单盐酸盐的合成及晶体结构. 有机化学，2003, 23(7), 710-713.
71. Liu CM, Gao S, Hu HM, Jin XL, Kou, HZ. Hydrothermal syntheses and crystal structures of two-dimensional (2D) layerd vanadium oxide complexes: M(bipy)(H2O)V2O6 (M=Ni, Co, bipy=bipyridine) and [Ni(bipy)2V6O17], J. Chem. Soc., Dalton Trans. 2002, 598-601.
72. Sun WH, Shao CX, Chen Y, Hu HM, Sheldon RA, Wang HG, Leng XB and Jin XL, Controllable supramolecular assembly by pi-pi interactions: Cobalt(II) and copper(II) complexes with benzimidazole derivatives. Organometallics, 2002, 21, 4350-4355.
73. Liu CM, Zhang DQ, Xiong M, Dai MQ, Hu HM, Zhu DB. Hydrothermal synthesis, crystal structures and magnetic properties of two bimetallic cage cluster vanadate complexes [Co(phen)2]2V4O12 and [Co(2,2’-bipy)2V4O12. J. Coord. Chem. 2002, 55, 1327-1335.
74. Sun WH, Li ZL, Hu HM, Wu B, Yang HB, Zhu N, Leng XB, Wang HG. Synthesis and characterization of novel nickel (II) complexes bearing N, P ligands and their catalytic activity in ethylene oligomerization. New J Chem. 2002, 26, 1474-1478.
75. Liu CM, Zhang DQ, Qin AJ, Ye C, Hu HM, Zhu DB. A novel nickel (II) complex adopting a cis-configuration: solvothermal synthesis and crystal structure of [NiL2(H2O)4] (L=1,4-dihydropyrazine-2,3-dione-5,6-dicarboxylate). Eur. J. Inorg. Chem. 2002, 1595-1598.
76. Shen XP, Zou JZ, Li BL, Hu HM, Xu Z. A novel self-assembled supramolecular complex {[Cu(II)(en)2?H2O][Cu(I)2(CN)4]}n with honeycomb-like structure and its adsorption properties. Chin. J. Chem. 2002, 20, 1472-1476.
77. Zhang DQ, Ding L, Xu W, Hu HM, Zhu DB, Huang YH, Fang DC. 1D silver (I) complex of nitronyl nitroxide with strong spin-spin interaction through silver(I) ion. Chem. Commun. 2002, 44-45.
78. Jia CY, Zhang DQ, Liu CM, Xu W, Hu HM, Zhu DB. Novel silver(I) complexes derived from tetrakis(methylthio)tetrathiafulvalene and bis(ethylenedithio) tetrathiafulvalene with 3D and 1D structures. New J Chem. 2002, 490-194.
79. Liu CM, Gao S, Hu HM, Wang ZM. A novel bimetallic cage complex constructed from six V4Co pentatomic rings: hydrothermal synthesis and crystal structure of [2,2’-Py2NH]2Co]3V8O23. Chem. Commun. 2001, 1636-1637.
80. Zou YQ, Li X, Li Y, Hu HM. Tetrakis(?-2,3-dimethoxybenzoato)bis[(2,2’-bi pyridine)(2,3-dimethoxybenzoato)lanthanum(III)]. Acta Cryst. 2001, C57, 1048- 1050.
81. Long DL, Cui CP, Hu HM, Chen JT, Ji ZP, Zhang YD, Huang JS. Non-linear optical absorption of [{Ni(mnt)2}2]2- and its unique counter ion, a disodium triple-decker dication [Na-2(benzo-15-crown-5)3 (H2O)2]2+. Inorg. Chem. Acta, 2000,298,125-131.
82. Wang QH, Long DL, Hu HM, Cui Y, Huang JS. Syntheses, crystal structures and electronic spectra of mixed-ligand zinc(II) complexes with diimines and dithiolates. J. Coord. Chem. 2000, 49(3), 201-209.
83. Lin SH, Wang ZQ, Zhang BH, Hu HM, Huang JS. Crystal structure of tris(2,2’-bipyridine)nickel(II) tetrachlorozincate, 结构化学, 2000, 19(2), 95-98.
84. Hu HM, Huang XY, Sun HS, Long DL, Huang JS, You XZ. Synthesis, crystal structure and magnetic properties of a thiocyanate bridged one-dimensional chain copper(II) complex: {[(232-tet)Cu(NCS)](ClO4)}n. J. Coord. Chem. 1999, 47(4), 531-540.
85. Cai H, Hu HM, Chen WZ, Zhu HG, You XZ. A novel three-dimensional framework: Self-assembly of AgNO3 and pyrimidine. Chem. Lett. 1999, (3), 221-222.
86. Long DL, Hu HM, Chen JT and Huang JS. [La(NO3)2(Ph3PO)4]2 [Ni(C4N2S2)2]. 2CH3OH, Acat Cryst. 1999, C55(10), 1662-1664.
87. Zhu HG, Yu Z, You XZ, Hu HM, Huang XY. The crystal and molecular structure of bis(melamine) silver(I) perchlorate Ag(C3H6N6)2ClO4. J. Chem. Crystallogr. 1999, 29(2), 239-242.
88. Sun HS, Zhao Q, Liu YJ, Hu HM, You XZ, Zhou ZY. Synthesis and characterization of complexes of Me3M (M = Al, Ga) or Et3In with bis(dimethylamino)-2-propanol. X-ray crystal structure of the [Me2GaOCH(CH2NMe2)2]2 dimer. J. Coord. Chem. 1999, 47(3), 459-465.
89. Long DL, Hu HM, Chen JT, Huang JS. [Ni{(CH3)2SO}6]I-4, a redetermination and reinterpretation. ACTA CRYST, 1999, C55(3), 339-341.
90. Hu HM, Long DL, Zeng HY, Cheng WD & Huang JS, A redetermination of bis(2-aminomethylpyridine)diperchloratocopper(II), Acta Cryst. 1999, C55(5). IUC9900049.
91. Cai, Hu; Hu, Huai-Ming; Chen, Wan-Zhi; Xu, Yan; You, Xiao-Zeng. 1,4-Bis(4H-1,2,4-triazol-4-yl)benzene monohydrate. Acta Cryst. Section C: Crystal Structure Communications. 1999, C55(8), IUC9900082.
92. Hu HM, Sun HS, Zhao Q, Yu Z, Huang XY, You XZ. Synthesis, crystal structure and magnetic properties of an imidazolate bridged dinuclear nickel(II) complex: ?-(Im)-[(232-TET)Ni]2(ClO4)3. J. Coord. Chem. 1998, 43(4), 361-369.
93. Hu HM, Sun HS, Duan CY, Zhao Q, You XZ, Zhou ZY, Zhou XG, (Carbonato-O,O') bis(1,2-thanediamine-N,N')cobalt(III) perchlorate. Acta Cryst. 1997, C53(8), 1014-1015.
94. Hu HM, Sun HS, Huang XY, Chen XH, Liu YJ, You XZ, meso-5,5,7,12,12,14-hexa- methyl-1,4,8,11-tetraazacyclotetradecane dihydroperchlorate monohydrate, ACTA CRYST, 1997, C53(5), 588-590.
95. Hu HM, Sun HS, Chen XH, Zhao Q, Pan Y, Huang XY, You XZ. (Diethylenetriamine) (imidazole)(thiocyanato)copper(II) perchlorate. Acta Cryst. 1997, C53(3),276-278.
96. Yu SY, Wang QM, Wu B, Wu XT, Hu HM, Wang LF, Wu AX. Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)].KSCN.CH3CN.3H2O (L is a deprotonated phenol-based N8O3 cryptand), Polyhedron, 1997, 16(2), 321-325.
97. 胡怀明， 孙红随， 高忆慈， 彭周人. 三甲基胺氧化物希土配合物的振动光谱和配位结构研究. 无机化学学报, 1997, 13(2), 124-127.
98. 陈景文， 廖宜勇， 冯流， 黄庆国， 韩朔睽， 王连生， 胡怀明，陆国元， 赵焘南. 应用量子化学MNDO方法预测取代氮杂环类化合物的生物活性, 科学通报, 1997, 42(2), 157-159.
99. Chen JW, Huang QG, Wang LS, Hu HM, Zhang Z. Using AM1 Hamiltonian and factor analysis in prediction of partition properties for phenylthio, phenylsulfinyl and phenylsulfonyl acetates. CHEMOSPHERE, 1996, 33(12), 2565-2575.
100. Hu HM, Sun HS, You XZ, Huang XY. (Acetato-O)(meso-5,5,7,12,12,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane-N,N',N'',N''')zinc(II) perchlorate mono- hydrate, ACTA CRYST, 1996, C52(8), 1946-1948.
101. Chen JW, Feng L, Liao YY, Wang LS, Hu HM. Using AM1 Hamiltonian in quantitative structure-properties relationship studies of alkyl (1-phenylsulfonyl) cycloalkane-carboxylates. Chemosphere. 1996, 33(3), 537-546.
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